Alkynylation of aryl halides with perfluoro-tagged palladium nanoparticles immobilized on silica gel under aerobic, copper- and phosphine-free conditions in water.

نویسندگان

  • Roberta Bernini
  • Sandro Cacchi
  • Giancarlo Fabrizi
  • Giovanni Forte
  • Francesco Petrucci
  • Alessandro Prastaro
  • Sandra Niembro
  • Alexandr Shafir
  • Adelina Vallribera
چکیده

The utilization of perfluoro-tagged palladium nanoparticles immobilized on fluorous silica gel through fluorous-fluorous interactions (Pd(np)-/FSG) or linked to silica gel by covalent bonds (Pd(np)-) in the alkynylation of terminal alkynes with aryl halides under aerobic, copper- and phosphine-free conditions in water, and their recovery and re-utilization, is described.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 7 11  شماره 

صفحات  -

تاریخ انتشار 2009